2. Mr. and Mrs. Smith (2005)
via franlouise.com
This list wouldn’t be complete without the infamous film that led Jolie into the arms of the then-very much married Brad Pitt. Even from the promotional posters of the romantic comedy action film Mr. and Mrs. Smith, it was clear as day that the chemistry between Jolie and Pitt was palpable. In the film, they play a seemingly boring married couple who are both clandestine assassins by night. Needless to say, angry sex never looked that hot.
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