5. Ritchie Humphreys, 154.3 km/h
We all expect the likes of Roberto Carlos and David Beckham to be in such a list, but Ritchie Humphreys? Yes, you read that right. Humphreys currently plays for League One Chesterfield, but back in 1996 he was playing for Sheffield Wednesday. It was his first season with Sheffield, and he had the best start he could ever hope. Ritchie Humphreys scored from inside the box against Aston Villa; his shot was clocked at 95.9 mph.
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