1. Angelina Jolie
In what was the hottest gossip story around town, Angelina Jolie and Brad Pitt came into the picture while Pitt was still married to Jennifer Aniston in 2004. The two actors met on the set of Mr. and Mrs. Smith and sources said that the two had obvious chemistry. Although the co-stars denied prior allegations of an affair, Aniston had enough of being in denial of the rumors and was left with no choice but to file for divorce in 2005. Unsurprisingly, Brangelina was born and became one of Hollywood’s high-profile couple. It was a devastating time for the Friends actress but she went on to marry Justin Theroux earlier this year.
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