11. Angelina Jolie and Billy Bob Thornton
Angelina Jolie and Billy Bob Thornton go down as one of the weirdest celebrity couples of all time. There was a time when the pair wore a vile of each other’s blood around their necks, however, their bizarre relationship came to an end in 2003 only three years after they said “ I do.”
While their relationship was unusual, their divorce went better than most Hollywood relationships. Thorton and Jolie still have an incredible amount of love and respect for one another, but they know that they are not meant to be together.
Thorton said “We had a great time together. We had a great marriage and I chickened out because I didn’t feel good enough. That’s all that happened. It was no big deal, we never hated each other.”
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