The 10 messiest and most public celebrity breakups ever (With Pictures)

6. Brad Pitt and Jennifer Aniston

Brad Pitt and Angelina Jolie may be a Hollywood super couple these days, but don’t forget that Brad Pitt was still married to Jennifer Aniston when he met Jolie on the set of Mr. And Mrs. Smith. It was very scandalous, but it was also a pretty good movie.