6. George C. Scott
Actor George C. Scott established an amazing career in Hollywood, and he was also married to the same woman twice. He married Colleen Dewhurst in 1960 and they remained together until 1965, but they managed to work out their differences and tried again, marrying for the second time in 1967 before finally calling it quits in 1972. They had two children together, Alexander, born in 1960 and Cambell, born in 1961.
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