5. Jennifer Aniston, Brad Pitt
Jennifer Aniston could not see herself working with Brad Pitt on a motion picture, simply because he completely left her hanging in 2005 when he ran off with Angelina Jolie. Brad announced his divorce from the Friends co-star, and within weeks, he had moved in with Angie. There was a lot of hurt surrounding Jennifer and Brad at that particular time. Jennifer supposedly felt betrayed to some degree; she loved Brad with all her heart and then learns that he wants a divorce so that he can be with his movie co-star. Ouch.
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