3. Angelina Jolie and Brad Pitt – Mr. and Mrs. Smith
Sometimes to show someone you love them, you have to try to kill them. That’s the message in Mr. and Mrs. Smith and it was through that message that Brad Pitt and Angelina Jolie first fell for each other. It was here on the set of this strange movie that Brangelina formed. Was Pitt technically still married to Jennifer Aniston? Yes, but they were going through the divorce settlement. Did the weird domestic abuse/sexual fantasy stuff on the set of the film encourage the attraction between the two stars Pitt and Jolie? Impossible to know, but we will say yes. Since then, Pitt and Jolie have been married and adopted a small nation of children to field a football team at Thanksgiving.
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